This name is a synonym of Psephellus czirkejensis (Husseinov) Greuter.
The record derives from Tropicos
(data supplied on 2012-04-18)
which reports it as a synonym (record 100377017) with original publication details: 4: 156 1876.
This name record (from Tropicos) was not included in version 1 of The Plant List. It is possible the same name was included from a different data source, to check this you can search for Centaurea amblyolepis in version 1 of The Plant List.